Microstructure and Properties of CoCrFeNiTi-Ti2AlC@Ni high-Entropy Alloy Composite Coatings by Ultra-high Speed Laser Cladding
In this paper, the CoCrFeNiTi- Ti2AlC@Ni high entropy alloy self-lubricating composite coating was prepared on the surface of Cr12MoV die steel by using the ultra-high speed laser cladding technology. Its phase composition, microstructure, element distribution, nano-hardness, wear resistance and anti-deformation ability were studied. The research results show that after adding Ti2AlC into the coating, there are relatively significant changes in both its microstructure and mechanical properties. From the perspective of microstructure, under the action of Ti2AlC, the grains are distributed more densely and uniformly, demonstrating good microstructure characteristics. In terms of mechanical properties, under the effect of grain refinement strengthening and the pinning effect of the newly generated phases, the indentation depth of the coating decreases from 1212 nm to 989 nm, and the elastic modulus increases from 204.06 Gpa to 228 Gpa, showing good resistance to plastic deformation. The nano-hardness of the coating increases from 8.65 Gpa to 12.57 Gpa. Moreover, Ti2AlC plays a pivotal role in reducing friction during the friction process. Therefore, under the synergistic effect of high hardness and self-lubrication, the wear resistance of the coating is improved, and the wear resistance of the coating reaches the best when it is 3%. At this time, the wear scar is the narrowest and the shallowest, the coating wear is the most uniform, and the friction coefficient decreases from 0.528 to 0.481.
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