eLibrary
  • Home
  • Sources
  • Search
  • About

Synthesis and Corrosion Inhibition Performance Evaluation of 4-Pyridinecarboxaldehyde-1,4-phenylenediamine Mono-Schiff Base

Yuanfang Deng, Junlan Li, Yue Li, Yutong Wei, Li Li, Yu Zhang, Jiawang Shen, Jing Zhou, Chuan Lai, Ting Long
International Core Journal of Engineering, (2025), Vol.11, No.11, pp.1-11
Published: November 22, 2025
DOI: 10.6919/ICJE.202511_11(11).0001
PDF: Download Full Text PDF
Abstract

A planar rigid mono-Schiff base corrosion inhibitor, 4-pyridinecarboxaldehyde-1,4-phenylenediamine (PAM-4), was synthesized in this work. Nuclear magnetic resonance (NMR) spectroscopy confirmed the structure of the compound. The inhibitory effect of PAM-4 on mild steel in 1 mol/L HCl at 25°C, 35°C, and 45°C was assessed through weight loss measurements and electrochemical techniques. Scanning electron microscopy (SEM) was used to examine the surface morphology of mild steel before and after corrosion, demonstrating that PAM-4 provides effective protection. The results reveal that inhibitor concentration and temperature are key factors influencing performance. Inhibition efficiency improved with increasing PAM-4 concentration, achieving a maximum of 91.51% at 1600 mg/L. Conversely, elevated temperatures reduced the inhibition effect.

Keywords: Corrosion; Corrosion Inhibitor; Mono-Schiff Base; Mild Steel; Corrosion Inhibition Performance.
APA Citation: Yuanfang Deng, Junlan Li, Yue Li, Yutong Wei, Li Li, Yu Zhang, Jiawang Shen, Jing Zhou, Chuan Lai, Ting Long (2025). Synthesis and Corrosion Inhibition Performance Evaluation of 4-Pyridinecarboxaldehyde-1,4-phenylenediamine Mono-Schiff Base. International Core Journal of Engineering, 11(11), 1-11. https://doi.org/10.6919/ICJE.202511_11(11).0001

References

  1. El Azzouzi, M., Azzaoui, K., Warad, I., Hammouti, B., Shityakov, S., Sabbahi, R., ... & Zarrouk, A. (2022). Moroccan, Mauritania, and senegalese gum Arabic variants as green corrosion inhibitors for mild steel in HCl: Weight loss, electrochemical, AFM and XPS studies. Journal of Molecular liquids, 347, 118354.
  2. Kumar, H., & Dhanda, T. (2021). Cyclohexylamine an effective corrosion inhibitor for mild steel in 0.1 N H2SO4: experimental and theoretical (molecular dynamics simulation and FMO) study. Journal of Molecular Liquids, 327, 114847.
  3. Hegazy, M. A., El-Tabei, A. S., Bedair, A. H., & Sadeq, M. A. (2015). Synthesis and inhibitive performance of novel cationic and gemini surfactants on carbon steel corrosion in 0.5 M H₂SO₄ solution.
  4. Jeeva, M., Prabhu, G. V., Boobalan, M. S., & Rajesh, C. M. (2015). Interactions and inhibition effect of urea-derived Mannich bases on a mild steel surface in HCl. The Journal of Physical Chemistry C, 119(38), 22025-22043.
  5. Murthy, R., Gupta, P., & Sundaresan, C. N. (2020). Theoretical and electrochemical evaluation of 2-thioureidobenzheteroazoles as potent corrosion inhibitors for mild steel in 2 M HCl solution. Journal of Molecular Liquids, 319, 114081.
  6. Golchinvafa, A., Anijdan, S. M., Sabzi, M., & Sadeghi, M. (2020). The effect of natural inhibitor concentration of Fumaria officinalis and temperature on corrosion protection mechanism in API X80 pipeline steel in 1 M H2SO4 solution. International Journal of Pressure Vessels and Piping, 188, 104241.
  7. Bedair, M. A., El-Sabbah, M. M. B., Fouda, A. S., & Elaryian, H. M. (2017). Synthesis, electrochemical and quantum chemical studies of some prepared surfactants based on azodye and Schiff base as corrosion inhibitors for steel in acid medium. Corrosion science, 128, 54-72.
  8. Kalaiselvi, P., Chellammal, S., Palanichamy, S., & Subramanian, G. (2010). Artemisia pallens as corrosion inhibitor for mild steel in HCl medium. Materials Chemistry and Physics, 120(2-3), 643-648.
  9. Fakhry, H., El Faydy, M., Benhiba, F., Laabaissi, T., Bouassiria, M., Allali, M., ... & Zarrouk, A. (2021). A newly synthesized quinoline derivative as corrosion inhibitor for mild steel in molar acid medium: Characterization (SEM/EDS), experimental and theoretical approach. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 610, 125746.
  10. Ehsani, A., Mahjani, M. G., Moshrefi, R., Mostaanzadeh, H., & Shayeh, J. S. (2014). Electrochemical and DFT study on the inhibition of 316L stainless steel corrosion in acidic medium by 1-(4-nitrophenyl)-5-amino-1 H-tetrazole. RSC Advances, 4(38), 20031-20037.
  11. Fernandes, C. M., Alvarez, L. X., dos Santos, N. E., Barrios, A. C. M., & Ponzio, E. A. (2019). Green synthesis of 1-benzyl-4-phenyl-1H-1, 2, 3-triazole, its application as corrosion inhibitor for mild steel in acidic medium and new approach of classical electrochemical analyses. Corrosion Science, 149, 185-194.
  12. Lgaz, H., Salghi, R., & Ali, I. H. (2018). Corrosion inhibition behavior of 9-hydroxyrisperidone as a green corrosion inhibitor for mild steel in hydrochloric acid: electrochemical, DFT and MD simulations studies. International Journal of Electrochemical Science, 13(1), 250-264.
  13. Pandey, A., Singh, B., Verma, C., & Ebenso, E. E. (2017). Synthesis, characterization and corrosion inhibition potential of two novel Schiff bases on mild steel in acidic medium. RSC advances, 7(74), 47148-47163.
  14. Gupta, R. K., Malviya, M., Verma, C., & Quraishi, M. A. (2017). Aminoazobenzene and diaminoazobenzene functionalized graphene oxides as novel class of corrosion inhibitors for mild steel: experimental and DFT studies. Materials Chemistry and Physics, 198, 360-373.
  15. Murmu, M., Saha, S. K., Murmu, N. C., & Banerjee, P. (2019). Effect of stereochemical conformation into the corrosion inhibitive behaviour of double azomethine based Schiff bases on mild steel surface in 1 mol L− 1 HCl medium: An experimental, density functional theory and molecular dynamics simulation study. Corrosion Science, 146, 134-151.
  16. Erami, R. S., Amirnasr, M., Meghdadi, S., Talebian, M., Farrokhpour, H., & Raeissi, K. (2019). Carboxamide derivatives as new corrosion inhibitors for mild steel protection in hydrochloric acid solution. Corrosion Science, 151, 190-197.
  17. Heydari, H., Talebian, M., Salarvand, Z., Raeissi, K., Bagheri, M., & Golozar, M. A. (2018). Comparison of two Schiff bases containing O-methyl and nitro substitutes for corrosion inhibiting of mild steel in 1 M HCl solution. Journal of Molecular liquids, 254, 177-187.
  18. Talebian, M., Raeissi, K., Atapour, M., Fernández-Pérez, B. M., Salarvand, Z., Meghdadi, S., ... & Souto, R. M. (2018). Inhibitive effect of sodium (E)-4-(4-nitrobenzylideneamino) benzoate on the corrosion of some metals in sodium chloride solution. Applied Surface Science, 447, 852-865.
  19. Dueke Eze, C. U., Madueke, N. A., Iroha, N. B., Maduelosi, N. J., Nnanna, L. A., Anadebe, V. C., & Chokor, A. A. (2022). Adsorption and inhibition study of N-(5-methoxy-2-hydroxybenzylidene) isonicotinohydrazide Schiff base on copper corrosion in 3.5% NaCl. Egyptian Journal of Petroleum, 31(2), 31-37.
© 2026 eLibrary · Stand on the shoulders of giants